The lighting of candles as sunset approaches on Friday is the traditional sign of the onset of Shabbat. After lighting the candles, it is customary to cover the eyes and recite a blessing. The Shabbat candle-lighting blessing can be found here, as can other key Shabbat blessings.
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Candle-Lighting Blessings for Yom Kippur
Blessings for beginning Yom Kippur in Hebrew, English, and transliteration.
Shabbat Blessings for Friday Night
Lighting the candles, saying Kiddush and other Shabbat dinner rituals.